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KMID : 1059519900340040340
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Journal of the Korean Chemical Society
1990 Volume.34 No. 4 p.340 ~ p.344
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Effect of High Pressure on Voltammetric Parameters of Bilirubin
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Bae Zun-Ung
Lee Heung-Lark
Kim Gyeong-Ho
Park Tae-Myung
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Abstract
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The pressure effect of voltammetric parameters for the oxidation of Bilirubin in 0.1 M TEAP-DMSO solution at micro Pt electrode has been investigated. With increasing the pressure from 1 to 1,800 bars, the peak potential of oxidation wave shifted to the more positive potential. The peak current becomes considerably smaller with increasing the pressure. The oxidation currents of Bilirubin was found to be diffusion controlled over all pressure ranges. The reversibility of oxidation step did not change with increasing pressure. The linear relationships were observed over all pressure ranges (1-1,800 bars).
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KEYWORD
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